June 2004 Regents #41-50

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AnswerExplanations
41 Using your knowledge of chemistry and the information in Reference Table H, which statement concerning propanone and water at 50°C is true?

(1) Propanone has a higher vapor pressure  and stronger intermolecular forces than water.
(2) Propanone has a higher vapor pressure and weaker intermolecular forces than water.
(3) Propanone has a lower vapor pressure  and stronger intermolecular forces than water.
(4) Propanone has a lower vapor pressure  and weaker intermolecular forces than water.

2more vapor weaker intermolecular forces
42 A solution that is at equilibrium must be

(1) concentrated    (3) saturated
(2) dilute                (4) unsaturated

3a solution is saturated when it is at equilibrium

dissolving and crystallizing are occurring at the same time

2increasing surface area, concentration, temperature or catalyst increase reaction rate

this is not LeChaterlier because it is not at equilibrium 

1Entropy 

gases>liquids>solids

45 Which pH indicates a basic solution?

(1) 1     (3) 7
(2) 5     (4) 12

 

 
4Bases above 7

acids below 7

45 carbons the triple bond is on 2
4use Reference tables
2oxidation charge goes up

electrons on the more positive side

22.69d is the half live so it will be reduced by 1/2
50 As the elements of Group 1 on the Periodic Table are considered in order of increasing atomic radius, the ionization energy of each successive element generally

(1) decreases
(2) increases
(3) remains the same

1going down group 1 it is easier to remove electrons as they are further from the nucleus

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