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Colligative Properties are based on the amount of a substance not what it is. Quantity not quality. Dissociation- when neutral combinations of particles separate into ions while in aqueous solution
Up to this point you have only thought about solution as a particle dissolved in water. This is true for many covalent compounds. They remain intact. (1 mole of particles) C6H12O6(s) ==>C6H12O6(aq) (1 mole of particles) Now we have to go back and remember what happens to Ionic compounds when they dissolve in water. Ionic compounds dissociate. (1 mole of particles) NaCl(s) ==> Na+(aq) + Cl-(aq) (2 moles of particles) (1 mole of particles) CaCl2(s) ==> Ca2+(aq) + 2Cl-(aq) (3 moles of particles) (1 mole of particles) Al(NO3)3(s) ==>Al3+(aq) + 3NO3-(aq) (4 moles of particles) Acids Ionize (covalent) (1 mole of particles) HCl(g) ==> H+(aq) + Cl-(aq) (2 moles of particles) SO WE HAVE MORE PARTICLES THEN WE THOUGHT van't hoff Factor (i)= the number of moles of particles after a substance has dissolved Boiling Point Elevation-The boiling point of a solvent will increase when another compound is dissolved in it. In other words- the more solute particles (van't hoff) you add the higher the boiling point. Advanced Description-When a solute is added to a solvent, the vapor pressure of the solvent (above the resulting solution) is less than the vapor pressure above the pure solvent. The boiling point of a solution, then, will be greater than the boiling point of the pure solvent because the solution (which has a lower vapor pressure) will need to be heated to a higher temperature in order for the vapor pressure to become equal to the external pressure (i.e., the boiling point). Freezing Point Depression- The freezing point of a solvent will decrease when another compound is dissolved in it. Regents Questions-follow the link for the answer and explanation Jan 2004 #13 Compared to pure water, an aqueous solution of calcium chloride has a Aug 2009 #19 How do the boiling point and freezing point of a solution of water and calcium chloride at standard pressure compare to the boiling point and freezing point of water at standard pressure? Jan 2003 #19 What occurs when NaCl(s) is added to water? Jan. 2007 #19 Compared to a 2.0 M aqueous solution of NaCl at 1 atmosphere, a 3.0 M aqueous solution of NaCl at 1 atmosphere has a June 2003#23 At standard pressure when NaCl is added to water, the solution will have a Jan 2010#39 Which solution has the highest boiling point at standard pressure? on to Boiling Point Elevation and Freezing Point Depression Calculations |