Electroylsis

 
 

Electrolysis

This reaction as written has a negative potential.  It will not occur spontaneously.  Instead, it is the reverse process that will readily occur.  To drive a nonspontaneous redox reaction, a potential greater than the cell potential is applied from an external source.  This process is called electrolysis.

Note- Law of attraction.

The positive ions head towards the negative electrode. Their charge reduces to zero. So the negative electrode is the called the cathode.

The negative ions head towards the positive electrode. Their charge increases to zero (oxidation). So the positive electrode is the called the anode.

 

2 H2O(l)  -->  O2(g)  +  2H2(g)

Electrolysis of water

2 NaCl(l)  -->  2 Na(l)  +  Cl2(g)

Electrolysis of salt